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Hydrogenation of aromatics with [Ru(g5-C5H5)Cl(TPPDS)2] in biphasic medium

dc.rights.licensehttp://creativecommons.org/licenses/by-nc-sa/3.0/ve/
dc.contributor.authorSuárez B., Trino
dc.contributor.authorGuzmán, Angie
dc.contributor.authorFontal, Bernardo
dc.contributor.authorReyes, Marisela
dc.contributor.authorBellandi, Fernando
dc.contributor.authorContreras, Ricardo Rafael
dc.contributor.authorCancines, Pedro
dc.contributor.authorLéon, Gustavo
dc.contributor.authorRojas, Loguard
dc.date.accessioned2011-08-16T19:19:25Z
dc.date.available2011-08-16T19:19:25Z
dc.date.issued2011-08-16T19:19:25Z
dc.identifier.urihttp://www.saber.ula.ve/handle/123456789/33644
dc.description.abstract[Ru(g5-C5H5)Cl(TPPDS)2], [TPPDS=P(C6H5)(C6H4SO3 ))2] in biphasic (n-heptane/water) medium hydrogenates toluene, benzene and m-xylene (105 C, 1400 psig H2, substrate/catalyst=600:1, 4 h) and in toluene hydrogenation gives methylcyclohexane. Catalytic activity increases with temperature, H2 pressure, ionic strength, and pH lower than 10. The catalytic water solution can be reused several times with little activity loss.es_VE
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleHydrogenation of aromatics with [Ru(g5-C5H5)Cl(TPPDS)2] in biphasic mediumes_VE
dc.typeinfo:eu-repo/semantics/article
dc.description.emailsuarez@ula.vees_VE
dc.description.emailfontal@ula.ve, bfontal@hotmail.comes_VE
dc.description.emailreyes@ula.vees_VE
dc.description.emailbellandi@ula.vees_VE
dc.description.emailcancines@ula.vees_VE
dc.description.emailricardo@ula.vees_VE
dc.publisher.paisVenezuelaes_VE
dc.subject.facultadFacultad de Cienciases_VE
dc.subject.institucionUniversidad de Los Andeses_VE
dc.subject.thematiccategoryQuímicaes_VE
dc.subject.tipoArtículoses_VE
dc.type.mediaTextoes_VE


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